Characters who are biologically related to villains.
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- Sailor Saturn
- Sally Iverson
- Satine Kryze
- Scorpius Malfoy
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- Scud
- Sheriff Toadster
- Shido Itsuka
- Shmi Skywalker
- Simba
- Skeeter McArthur
- Slime Princess
- Snow White (Disney)
- Snow White (Snow White and the Huntsman)
- Soren (Guardians of Ga'Hoole)
- Spike (My Little Pony: Friendship is Magic)
- Spock
- Stewie Griffin
- Sylvester J. Pussycat Jr.
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